When towing the caravan my alternator switches when it detects the caravan is there from being intelligent to being a dumb 14.4v alternator. There was no hardware added when the towbar was fitted merely some reprogramming of the ECU.
Is there a reason why an RV couldn't be reprogrammed to take account if the extra load when charging a Li battery in the same way my car does.
Thinking about this as it stands an intelligent alternator is not going to fully charge an extra 100Ah LA battery so they must already reprogram or similar when fitting an extra battery.
It's been interesting watching the alternator voltage curve when in intelligent mode, most of the time it sits, as you say, at about 13v however when on engine overrun/braking it reaches 14.4v that's about the only time it does apart from when the vehicle is first started.