Thanks for the help guys!
@ditchcrawler That diagram is really helpful, I 'get it' a lot better now.
@Tony Brooks I understand where the confusion lies, when you said "no pumped hot water" I thought you meant its inadvisable to use a backboiler as a calorifier heat source all together. Thanks for clarifying
One question I do have is, on most of the backboiler units I've seen there's only two valves for pipework, one hot out and one cold return, the diagram looks as though it'd require 3. I was thinking, could the calorifier go at the back of the chain of rads and work "like a radiator" (in terms of its placement in the circuit), instead of being at the front end, therefore avoiding the need for 3 outlets on the backboiler? Then, if I wanted to just heat the calorifier as priority, I could isolate the rads to ensure the heat travels to the calorifier at the back, and open them again once hot to dump the excess heat. Only issue I can see with this is that (I imagine) the pump would be working pretty hard to get the water to the back of the boat, up the pipework, through the calorifier and back into the hot taps, or are narrowboat pumps 'ard enough to hack it?
The idea about the pipe going straight through the heat source is interesting and probably would be cheaper, but I have concerns about trying to drill through a cast iron stove, I've heard they don't like it as their quite brittle, could be wrong though.
Overall though, hope restored! Thanks again!