Hey thanks for your reply Tony.
yes sorry hot water tank - calorifier.
It was gravity fed so no pump and we had an expansion tank on the domestic hot water. We did have two PRV on the tank itself as we installed ourselves so seems so strange they both failed? One pressure and one thermo I think? We do have a pump for the cold water which obviously replaces water in the hot water tank but that was working fine.
I don’t think there was an air leak into the stove as it was always a bit hard to get going and never burned that well (may be due to the damp leak).
it seems so strange as to why it failed we even got someone to come and look at it before it burst and he said it looked fine. The water temp in the calorifier was obviously too hot which built up pressure but no idea why it burst before the expansion tank and PRV were activated? The system was brand new so shouldn’t of had anything blocking water flow