Thank you for your assistance everyone, really helpful to a newbie!
There is a '1-2-both-off switch' on the narrowboat and checking the photos I took earlier, there does appear to be 2 x Yuasa 90ah/35 leisure batteries and a powerstart 100ah battery which I'm guessing is the starter battery, hopefully wired to position 1.
The label on the starter battery has an 'installed' on date sticker which only goes up to 2014, so presuming this is rather old!
Thinking about replacing all with these dual-purpose batteries, which will fit in the space well.
https://advancedbatterysupplies.co.uk/product/3-x-numax-cxv31mf-batteries-110ah-deep-cycle-battery/