Thanks very much Peter, I've sent you a PM. A chat would be excellent.
Starting from cold will always take longer with any system of course but these are really good points, thanks. Just to clarify, the stove is in fact rated at 12kw total, with roughly 7 going to boiler. It is in the main living space and the main source of heat. The living room radiator is an afterthought in many ways, and a relatively small additional expense for greater flexibility. In reality, the stove would be run hard in the evenings, but still kept ticking over full time in the winter, as is conventional.
and
again, really good points and making me triple check all of my thinking, thanks.
In reality, the rads will not be expected to do much during the day. They are primarily for putting some heat into the bedrooms in the evening and first thing. I've done loads of calculations for different scenarios and I'm more concerned about being able to dump enough heat in the evening when the store is at 90 and the boiler is still going strong!
I can see why that would make sense (on the TS thermosyphon), great input, thanks. Do you not think a vent on the heat sink side would help to reduce the risk of knocking in an overheat situation? Hmm, now I'm tempted to do both.