General non-Ruhton comments
Does C go back into the inlet side of any engine water pump. I would expect it to, so the pump can recirculate the returning water (until you close the valve). If so, be careful about what you do. On many engines this bypass is vital to stop local hotspots inside the water jacket overheating and locally boiling furring up.
If the Jabsco type pump is the circulating pump, then stopping it pumping water may not be a good idea in case friction allows the residual water in the pump to boil and damage the rubber impeller. I suspect there is more relevant plumbing than that shown.
I don't know if any hoses are involved, but some Renaults had a thermostat that fitted inside a coolant hose and secured by an external worm drive hose clip - Renault 4 I think and possibly Renault 5.
As far as the engine staying cold until the calorifier warms up, I don't think it is a particularly important issue, probably a more theoretical concern than a practical one. The same applies to the vast majority of boats equipped with calorifiers. Offhand, only Barrus seem to fit another "calorifier" thermostat to mitigate it. However, the calorifier feed hoses used on other boats are typically about 1/2" bore, so will restrict the flow to a degree.
Is this direct canal water cooled, heat exchanger cooled, or skin tank cooled, because the plumbing is likely to differ. Wet or dry exhaust.